Fundamentals of Physics Extended (10th Edition)

Published by Wiley
ISBN 10: 1-11823-072-8
ISBN 13: 978-1-11823-072-5

Chapter 20 - Entropy and the Second Law of Thermodynamics - Problems - Page 608: 63c

Answer

$\Delta S = -23.04J/K$

Work Step by Step

Isothermal process equation of an ideal gas is $Q = W$ $\int \frac{dQ}{T}= \int \frac{p dV}{(pV/nR)} $ $\Delta S= nR \int \frac{dV}{V}$ $\Delta S = nR ln (\frac{V_f}{V_i}) $ From the question, $n = 4.00 mol, V_2 = 2.00V_1$, but going back to the initial state, so $V_f = 1.00$ and $V_i = 2.00$ $\Delta S = (4.00)(8.31 J/mol.K) ln (\frac{1.0}{2.0}) $ $\Delta S = -23.04J/K$ The negative sign implies the compression state.
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