Chemistry: The Central Science (13th Edition)

Published by Prentice Hall
ISBN 10: 0321910419
ISBN 13: 978-0-32191-041-7

Chapter 16 - Acid-Base Equilibria - Exercises - Page 718: 16.46c

Answer

$[OH^-] = 4.2 \times 10^{-4}$ $pH = 10.623$

Work Step by Step

1. Calculate the concentration of $Ca(OH)_2$ after the dilution: $C_i * V_i = C_f * V_f$ $0.0105 * 0.010 = C_f * 0.500$ $C_f = \frac{0.000105}{0.500}$ $C_f = 2.1 \times 10^{-4}M$ 2. Since $Ca(OH)_2$ is a strong base, and each mol of $Ca(OH)_2$ has 2 $OH^-$: $[OH^-] = 2*[Ca(OH)_2]$ $[OH^-] = 2*2.1\times10^{-4} = 4.2 \times 10^{-4}M$ 3. Find the pH: $pOH = -log[OH^-]$ $pOH = -log(4.2\times10^{-4}) = 3.377$ $pH = 14 - pOH$ $pH = 14 - 3.377 = 10.623$
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