Chemistry: The Central Science (13th Edition)

Published by Prentice Hall
ISBN 10: 0321910419
ISBN 13: 978-0-32191-041-7

Chapter 16 - Acid-Base Equilibria - Exercises - Page 718: 16.44d

Answer

$pH = 1.89$

Work Step by Step

1. Find the concentrations of $HCl$ and $HI$ after the dilution: Total volume : $50ml + 125ml = 175ml$ $HCl:$ $C_i * V_i = C_f * V_f$ $0.020 * 0.050 = C_f * 0.175$ $0.001 = C_f * 0.175$ $C_f = 5.71 \times 10^{-3}M$ $HI:$ $C_i * V_i = C_f * V_f$ $0.01 * 0.125 = C_f * 0.175$ $0.00125 = C_f * 0.175$ $C_f = 7.14 \times 10^{-3}M$ 2. Since they are strong acids: $[HCl] +[HI] = [H^+]$ $5.71 \times 10^{-3} + 7.14 \times 10^{-3} = [H^+]$ $[H^+] = 1.285 \times 10^{-2}M$ 3. Calculate the pH: $pH = -log[H^+]$ $pH = -log(1.285 \times 10^{-2})$ $pH = 1.89$
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