Chemistry: The Central Science (13th Edition)

Published by Prentice Hall
ISBN 10: 0321910419
ISBN 13: 978-0-32191-041-7

Chapter 16 - Acid-Base Equilibria - Exercises - Page 718: 16.43d

Answer

$pH \approx 0.778$

Work Step by Step

1. Find the number of moles of $HBr$ and $HCl$: $HBr:$ $n(moles) = Concentration \times Volume(L)$ $n(moles) = 0.100 \times 0.01$ $n(moles) = 0.001$ $HCl:$ $n(moles) =0.200 \times 0.02$ $n(moles) = 0.004$ 2. Find the number of $H^+$ moles: Since $HBr$ and $HCl$ are strong acids: $n(H^+) = n(HBr) + n(HCl)$ $n(H^+) = 0.001 + 0.004$ $n(H^+) = 0.005 moles$ 3. Find the concentration of $H^+$ $Total Volume = 20ml + 10ml = 30ml$ $Concentration = \frac{n(moles)}{V(L)}$ $[H^+] = \frac{0.005}{0.030}$ $[H^+] \approx 0.167$ 3. Calculate the pH: $pH = -log[H^+]$ $pH \approx -log(0.167)$ $pH \approx 0.778$
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