Chemistry: The Central Science (13th Edition)

Published by Prentice Hall
ISBN 10: 0321910419
ISBN 13: 978-0-32191-041-7

Chapter 16 - Acid-Base Equilibria - Exercises - Page 719: 16.72

Answer

$pH \approx 11.231$

Work Step by Step

1. Write the Ka equation: $*[OH^-] = [HBrO] = x$ $4 \times 10^{-6} = \frac{x^2}{0.724 - x}$ * Because x is very small, we can disconsider the value of x in the subtraction. $4 \times 10^{-6} = \frac{x^2}{0.724 }$ $2.896 \times 10^{-6} = x ^2$ $ x = 1.702 \times 10^{-3}$ 2. Now, with $[OH^-]$, find the pOH, and them, the pH. $[OH^-] = 1.702 \times 10^{-3}$ $pOH = -log[OH^-] $ $pOH = -log(1.702 \times 10^{-3})$ $pOH = 2.769$ $pH = 14 - 2.769$ $pH = 11.231$
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