Chemistry: The Central Science (13th Edition)

Published by Prentice Hall
ISBN 10: 0321910419
ISBN 13: 978-0-32191-041-7

Chapter 16 - Acid-Base Equilibria - Exercises - Page 719: 16.54

Answer

$[BrCH_2COO^-] and [H_3O^+] = 0.0132M$ $[BrCH_2COOH] = 0.0868M$ $Ka = 2.007\times 10^{- 3}$

Work Step by Step

1. Drawing the equilibrium (ICE) table, we get these concentrations at equilibrium:** The image is in the end of this answer. -$[H_3O^+] = [BrCH_2COO^-] = x$ -$[BrCH_2COOH] = [BrCH_2COOH]_{initial} - x$ 2. Write the percent ionization equation, and find 'x': %ionization = $\frac{x}{[Initial Acid]} \times 100$ 13.2= $\frac{x}{ 0.1} \times 100$ 0.132= $\frac{x}{ 0.1}$ $ 0.0132= x$ Therefore: $[BrCH_2COO^-] and [H_3O^+] = 0.0132M$ And, $[BrCH_2COOH] = 0.0868M$ 3. Write the Ka equation, and find its value: $Ka = \frac{[H_3O^+][BrCH_2COO^-]}{ [BrCH_2COOH]}$ $Ka = \frac{x^2}{[InitialBrCH_2COOH] - x}$ $Ka = \frac{( 0.0132)^2}{ 0.1- 0.0132}$ $Ka = \frac{ 1.742\times 10^{- 4}}{ 0.0868}$ $Ka = 2.007\times 10^{- 3}$
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