Chemistry: The Central Science (13th Edition)

Published by Prentice Hall
ISBN 10: 0321910419
ISBN 13: 978-0-32191-041-7

Chapter 16 - Acid-Base Equilibria - Exercises - Page 719: 16.64a

Answer

4. %ionization: $\frac{1.796\times10^{-3}}{0.25} \times 100$% = 0.7184%

Work Step by Step

1. Write the Ka formula: $K_a = \frac{[C_2H_5COO^-][H^+]}{[C_2H_5COOH] - [H^+]}$ 2. Since $[H^+] = [C_2H_5COO^-]:$ $K_a = \frac{x^2}{[C_2H_5COOH]- x}$ $1.3 \times 10^{-5} = \frac{x^2}{0.25-x}$ $3.25 \times 10^{-6} - 1.3\times10^{-5}x = x^2$ $3.25 \times 10^{-6} - 1.3\times10^{-5}x - x^2 = 0$ 3. Find the value of x: $x_1 = \frac{-b - \sqrt {b^2-4ac}}{2a}$ $x_1 = \frac{1.3 \times 10^{-5} - \sqrt[] {(1.3\times10^{-5})^2 - 4 \times (-1) \times 3.25 \times 10^{-6}}}{-2}$ $x_1 = \frac{1.3\times10^{-5}-\sqrt {1.3 \times 10^{-5}}}{-2}$ $x_1 \approx 1.796 \times 10^{-3}$ * If we used $x_1 = \frac{-b + \sqrt {b^2-4ac}}{2a}$ the result would be negative. 4. %ionization: $\frac{1.796\times10^{-3}}{0.25} \times 100$ %= 0.7184%
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