Chemistry: The Central Science (13th Edition)

Published by Prentice Hall
ISBN 10: 0321910419
ISBN 13: 978-0-32191-041-7

Chapter 16 - Acid-Base Equilibria - Exercises - Page 719: 16.55

Answer

- The acetic acid concentration in the vinegar is 0.08931M.

Work Step by Step

1. Find the $[H_3O^+]$ value: $[H_3O^+] = 10^{-pH}$ $[H_3O^+] = 10^{- 2.9}$ $[H_3O^+] = 1.259 \times 10^{- 3}$ 2. Drawing the equilibrium (ICE) table we get these concentrations at equilibrium:** The image is in the end of this answer. -$[H_3O^+] = [Conj.Base] = x$ -$[Acetic acid] = [Acetic acid]_{initial} - x$ 3. Now, use the Ka and x values and equation to find the initial concentration value. $Ka = \frac{[H_3O^+][Conj.Base]}{ [Initial Acetic acid] - x}$ $ 1.8\times 10^{- 5}= \frac{[x^2]}{ [Initial Acetic acid] - x}$ $ 1.8\times 10^{- 5}= \frac{( 1.259\times 10^{- 3})^2}{[Initial Acetic acid] - 1.259\times 10^{- 3}}$ $[Initial Acetic acid] - 1.259\times 10^{- 3} = \frac{ 1.585\times 10^{- 6}}{ 1.8\times 10^{- 5}}$ $[Initial Acetic acid] - 1.259\times 10^{- 3} = 0.08805$ $[Initial Acetic acid] = 0.08805 + 1.259\times 10^{- 3}$ $[Initial Acetic acid] = 0.08931M$
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