Chemistry: The Central Science (13th Edition)

Published by Prentice Hall
ISBN 10: 0321910419
ISBN 13: 978-0-32191-041-7

Chapter 16 - Acid-Base Equilibria - Exercises - Page 719: 16.60c

Answer

pH = 9.63

Work Step by Step

1. Drawing the ICE table we get: -$[OH^-] = [B^+] = x$ -$[Base] = [Base]_{initial} - x$ For approximation, we consider: $[Base] = [Base]_{initial}$ 2. Now, use the Kb value and equation to find the 'x' value. $Kb = \frac{[OH^-][B^+]}{ [Base]}$ $Kb = 1.1 \times 10^{- 8}= \frac{x * x}{ 0.165}$ $Kb = 1.1 \times 10^{- 8}= \frac{x^2}{ 0.165}$ $ 1.81 \times 10^{- 9} = x^2$ $x = 4.26 \times 10^{- 5}$ 5% test: $\frac{ 4.26 \times 10^{- 5}}{0.165} \times 100\% = 0.0258\%$ %ionization < 5% : Right approximation. $[OH^-] = x = 4.26 \times 10^{-5}$ 3. Calculate the pH: $pOH = -log[OH^-]$ $pOH = -log( 4.26 \times 10^{- 5})$ $pOH = 4.37$ $pH + pOH = 14$ $pH + 4.37 = 14$ $pH = 9.63$
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