Chemistry: The Central Science (13th Edition)

Published by Prentice Hall
ISBN 10: 0321910419
ISBN 13: 978-0-32191-041-7

Chapter 16 - Acid-Base Equilibria - Exercises - Page 719: 16.63a

Answer

The percent ionization for this concentration is 0.698%.

Work Step by Step

Ka ($HN_3$): $1.9 \times 10^{-5}$ 1. Drawing the ICE table, we get: -$[H^+] = [A^-] = x$ -$[HA] = [HA]_{initial} - x$ For approximation, we consider: $[HA] = [HA]_{initial}$ 2. Now, use the Ka value and equation to find the 'x' value. $Ka = \frac{[H^+][A^-]}{ [HA]}$ $Ka = 1.9 \times 10^{- 5}= \frac{x * x}{ 0.4}$ $Ka = 1.9 \times 10^{- 5}= \frac{x^2}{ 0.4}$ $ 7.6 \times 10^{- 6} = x^2$ $x = 2.75 \times 10^{- 3}$ %Ionization : $\frac{ 2.75 \times 10^{- 3}}{0.4} \times 100\% = 0.689\%$ Since ionization < 5%, the acid concentration have a right approximation.
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