Fundamentals of Physics Extended (10th Edition)

Published by Wiley
ISBN 10: 1-11823-072-8
ISBN 13: 978-1-11823-072-5

Chapter 20 - Entropy and the Second Law of Thermodynamics - Problems - Page 604: 15c

Answer

Yes

Work Step by Step

Yes, they are consistent with the second law of thermodynamics. The change in entropy of the water-ice system is zero even though part of the cycle is irreversible throughout the whole cycle. Even, the system is not closed. To consider a closed system, we must include whatever exchanges energy with the ice and water. Suppose it is a constant temperature heat reservoir during the freezing portion of the cycle and a Bunsen burner during the melting portion. During freezing the entropy of the reservoir increases by 943 J/K. As far as the reservoir-water-ice system is concerned, the process is adiabatic and reversible, so its total entropy does not change. The melting process is irreversible, so the total entropy of the burner-water-ice system increases. The entropy of the burner either increases or else decreases by less than 943 J/K.
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