Answer
$\frac{\sqrt 5}{5}$
Work Step by Step
Let $cos^{-1}\frac{2}{3}=y$, we have $cos(y)=\frac{2}{3}, $ and
$tan(\frac{1}{2}cos^{-1}\frac{2}{3})=tan(\frac{y}{2})
=\sqrt {\frac{1-cos(y)}{1+cos(y)}}=\sqrt {\frac{1-2/3}{1+2/3}}=\frac{\sqrt 5}{5}$