Chemistry: The Central Science (13th Edition)

Published by Prentice Hall
ISBN 10: 0321910419
ISBN 13: 978-0-32191-041-7

Chapter 17 - Additional Aspects of Aqueous Equilibria - Exercises - Page 769: 17.44c

Answer

The pH of this solution is equal to $7.00$ (Neutral).

Work Step by Step

1000ml = 1L 24ml = 0.024 L 20ml = 0.02 L 1. Find the numbers of moles: $C(HClO_4) * V(HClO_4) = 0.125* 0.024 = 3 \times 10^{-3}$ moles $C(KOH) * V(KOH) = 0.15* 0.02 = 3 \times 10^{-3}$ moles 2. When the number of moles is equal, the reactants are totally consumed: $HClO_4(aq) + KOH(aq) -- \gt KClO_4(aq) + H_2O(l)$ - Total volume: 0.024 + 0.02 = 0.044L 3. So, those are the final concentrations: $[HClO_4] = 0.003 - 0.003 = 0$ mol. $[KOH] = 0.003 - 0.003 = 0$ mol - Therefore, the solution doesn't have any significant electrolyte: pH = 7 (Neutral)
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