Chemistry: The Central Science (13th Edition)

Published by Prentice Hall
ISBN 10: 0321910419
ISBN 13: 978-0-32191-041-7

Chapter 17 - Additional Aspects of Aqueous Equilibria - Exercises - Page 768: 17.17b

Answer

The percent ionization of butanoic acid in that solution is equal to 0.018%.

Work Step by Step

1. Drawing the ICE table we get these concentrations at the equilibrium: $HC_4H_7O_2(aq) + H_2O(l) \lt -- \gt C_4H_7O_2^-(aq) + H_3O^+(aq)$ Remember: Reactants at equilibrium = Initial Concentration - x And Products = Initial Concentration + x $[HC_4H_7O_2] = 0.0075 M - x$ $[C_4H_7O_2^-] = 0.085M + x$ $[H_3O^+] = 0 + x$ 2. Calculate 'x' using the $K_a$ expression. $ 1.5\times 10^{- 5} = \frac{[C_4H_7O_2^-][H_3O^+]}{[HC_4H_7O_2]}$ $ 1.5\times 10^{- 5} = \frac{( 0.085 + x )* x}{ 0.0075 - x}$ Considering 'x' has a very small value. $ 1.5\times 10^{- 5} = \frac{ 0.085 * x}{ 0.0075}$ $ 1.5\times 10^{- 5} \times \frac{0.0075}{0.085} = x$ $x = 1.32 \times 10^{-6}M$ Percent dissociation: $\frac{ 1.32\times 10^{- 6}}{ 0.0075} \times 100\% = 0.018\%$
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