Chemistry: The Central Science (13th Edition)

Published by Prentice Hall
ISBN 10: 0321910419
ISBN 13: 978-0-32191-041-7

Chapter 17 - Additional Aspects of Aqueous Equilibria - Exercises - Page 768: 17.29b

Answer

The ratio of $HC{O_3}^-$ to $H_2CO_3$ when the pH is 7.1 is : 5.4.

Work Step by Step

1. Calculate $[H_3O^+]$: $[H_3O^+] = 10^{-pH}$ $[H_3O^+] = 10^{- 7.1}$ $[H_3O^+] = 7.943 \times 10^{- 8}M$ 2. Write the $K_a$ equation, and find the ratio: $K_a = \frac{[H_3O^+][HC{O_3}^-]}{[H_2CO_3]}$ $4.3 \times 10^{-7} = \frac{7.943 \times 10^{-8}*[HC{O_3}^-]}{[H_2CO_3]}$ $\frac{4.3 \times 10^{-7}}{7.943 \times 10^{-8}} = \frac{[HC{O_3}^-]}{[H_2CO_3]}$ $5.413 = \frac{[HC{O_3}^-]}{[H_2CO_3]}$
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