Chemistry: The Central Science (13th Edition)

Published by Prentice Hall
ISBN 10: 0321910419
ISBN 13: 978-0-32191-041-7

Chapter 17 - Additional Aspects of Aqueous Equilibria - Exercises - Page 768: 17.15a

Answer

The $pH$ of this solution is equal to $4.73$.

Work Step by Step

1. Calculate the pKa Value $pKa = -log(Ka)$ $pKa = -log( 1.3 \times 10^{- 5})$ $pKa = 4.886$ 2. Check if the ratio is between 0.1 and 10: - $\frac{[Base]}{[Acid]} = \frac{0.06}{0.085}$ - 0.7058: It is. 3. Check if the compounds exceed the $K_a$ by 100 times or more: - $ \frac{0.06}{1.3 \times 10^{-5}} = 4615$ - $ \frac{0.085}{1.3 \times 10^{-5}} = 6537$ 4. Using the Henderson–Hasselbalch equation: $pH = pKa + log(\frac{[Base]}{[Acid]})$ $pH = 4.886 + log(\frac{0.06}{0.085})$ $pH = 4.886 + -0.1512$ $pH = 4.735$
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