Chemistry 12th Edition

Published by McGraw-Hill Education
ISBN 10: 0078021510
ISBN 13: 978-0-07802-151-0

Chapter 18 - Electrochemistry - Questions & Problems - Page 850: 18.15

Answer

Yes, $NO_{3}^{-}(aq)$ can oxidize $Mn^{2+}(aq)$ to $MnO_{4}^{-}(aq) $ under standard conditions.

Work Step by Step

$MnO_{4}^{-}(aq) + 8 H^{+}(aq) + 5e → Mn^{2+}(aq)+4 H_{2}O_{l} $ $ E^{\circ} = +1.51V$ $NO_{3}^{-}(aq) + 4 H^{+}(aq) + 3e → NO_{(g)}+ H_{2}O_{l} $ $ E^{\circ} = +0.96 V$ Since the standard reduction potential of $NO_{3}^{-}(aq) → NO_{(g)}$[+0.96 V] is less than $MnO_{4}^{-}(aq) → Mn^{2+}(aq)$ [+1.51 V], $NO_{3}^{-}(aq)$ can oxidize $Mn^{2+}(aq)$ to $MnO_{4}^{-}(aq) $ under standard conditions.
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