Chemistry: A Molecular Approach (3rd Edition)

Published by Prentice Hall
ISBN 10: 0321809246
ISBN 13: 978-0-32180-924-7

Chapter 3 - Sections 3.1-3.12 - Exercises - Cumulative Problems - Page 135: 134

Answer

$$C_9H_{11}O_2N$$

Work Step by Step

1. Find the empirical formula. n(benzocaine) = $\frac{3.54 \space g}{165 \space g/mol} = 0.0215 \space mol$ $$n(C) = n(CO_2) = \frac{8.49 \space g}{44.0 \space g/mol} = 0.193 \space mol$$ $$n(H) = 2 \times n(H_2O) = 2 \times \frac{2.14 \space g}{18.0 \space g/mol} = 0.238 \space mol$$ - Divide each amount by the amount of benzocaine. $$C_{\frac{0.193}{0.0215}}H_{\frac{0.238}{0.0215}}O_xN_y $$ $$C_9H_{11}O_xN_y$$ Second experiment: n(benzocaine) = $\frac{2.35 \space g}{165 \space g/mol} = 0.0142 \space mol$ $$n(N) = \frac{0.199 \space g}{14.0 \space g/mol} = 0.0142 \space mol$$ $$C_9H_{11}O_xN_{\frac{0.0142}{0.0142}}$$ $$C_9H_{11}O_xN$$ Without the oxygen, the molar mass of the compound is: M = 12.0 * 9 + 1.0 * 11 + 14.0 = 133 g/mol Thus: m(O) for 1 mol = 165 g - 133 g = 32 g $$n(O) = \frac{32 \space g}{16.0 \space g/mol} = 2 \space mol$$ $$C_9H_{11}O_2N$$
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