Chemistry: A Molecular Approach (3rd Edition)

Published by Prentice Hall
ISBN 10: 0321809246
ISBN 13: 978-0-32180-924-7

Chapter 3 - Sections 3.1-3.12 - Exercises - Cumulative Problems - Page 135: 128

Answer

$C_{6}H_{12}O_{6}$

Work Step by Step

Assume 100g of the compound. Convert the mass of each constituent element into moles by dividing by its molar mass: $40.00g\ C\times\frac{1mol}{12.01g}=3.331mol\ C$ $6.72g\ H\times\frac{1mol}{1.01g}=6.65mol\ H$ $53.28g\ O\times\frac{1mol}{16.00g}=3.330mol\ O$ Formulas have whole number subscripts so divide all the amounts by the smallest and round if the number is really close. $\frac{3.331mol\ C}{3.330}=1$ $\frac{6.65mol\ H}{3.330}=2$ $\frac{3.330mol\ O}{3.330}=1$ So the empirical formula for this compound is: $CH_{2}O$ Divide the molar mass of the compound by the molar mass of the empirical formula then multiply the subscripts of the empirical formula by this number. $180.16\frac{g}{mol}\div30.03\frac{g}{mol}=6$ So the molecular formula is $C_{6}H_{12}O_{6}$.
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