Chemistry: A Molecular Approach (3rd Edition)

Published by Prentice Hall
ISBN 10: 0321809246
ISBN 13: 978-0-32180-924-7

Chapter 3 - Sections 3.1-3.12 - Exercises - Cumulative Problems - Page 135: 127

Answer

$C_{18}H_{24}O_{2}$

Work Step by Step

Assume 100g of the compound. Convert the mass of each constituent element into moles by dividing by its molar mass: $79.37g\ C\times\frac{1mol}{12.01g}=6.609mol\ C$ $8.88g\ H\times\frac{1mol}{1.01g}=8.79mol\ H$ $11.75g\ O\times\frac{1mol}{16.00g}=0.7344mol\ O$ Formulas have whole number subscripts so divide all the amounts by the smallest and round if the number is really close. $\frac{6.609mol\ C}{0.7344}=9$ $\frac{8.79mol\ H}{0.7344}=12$ $\frac{0.7344mol\ O}{0.7344}=1$ So the empirical formula for this compound is: $C_{9}H_{12}O$ Divide the molar mass of the compound by the molar mass of the empirical formula and then multiply the subscripts of the empirical formula by this number. $272.37\frac{g}{mol}\div136.12\frac{g}{mol}= 2$ So the molecular formula is $C_{18}H_{24}O_{2}$.
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