Chemistry: A Molecular Approach (3rd Edition)

Published by Prentice Hall
ISBN 10: 0321809246
ISBN 13: 978-0-32180-924-7

Chapter 3 - Sections 3.1-3.12 - Exercises - Cumulative Problems - Page 135: 129

Answer

$$C_{18}H_{20}O_2$$

Work Step by Step

1. Find the empirical formula of equilin. $M(CO_2) = 44.0 \space g/mol$ $M(H_2O) = 18.0 \space g/mol$ $M(O_2) = 32.0 \space g/mol$ $$n(C) = n(CO_2) = \frac{39.61 \space g}{44.0 \space g/mol} = 0.900 \space mol$$ $$n(H) = 2 \times n(H_2O) = 2 \times \frac{9.01 \space g}{18.0 \space g/mol} = 1.00 \space mol$$ $$m(C) = 0.900 \space mol \times 12.0 \space g/mol = 10.8 \space g$$ $$m(H) = 1.00 \space mol \times 1.0 \space g/mol = 1.0 \space g$$ $$m(equilin) = m(C) + m(H) + m(O)$$ $$m(O) = m(equilin) - m(C) - m(H)$$ $$m(O) = 13.42 \space g - 10.8 \space g - 1.0 \space g = 1.6 \space g$$ $$n(O) = \frac{1.6 \space g}{16.0 \space g/mol} = 0.10 \space mol$$ $$equilin = C_{0.900}H_{1.00}O_{0.10}$$ $\div 0.10$ $$equilin = C_{9}H_{10}O_{1}$$ 2. Calculate its molar mass and find the proportion. $M(C_9H_{10}O) = 12.0 * 9 + 1.0 * 10 + 16.0 = 134.0 \space g/mol$ $$\frac{268.34 \space g/mol}{134.0 \space g/mol} \approx 2$$ Thus: $$equilin = 2 * C_9H_{10}O = C_{18}H_{20}O_2$$
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