Chemistry: A Molecular Approach (3rd Edition)

Published by Prentice Hall
ISBN 10: 0321809246
ISBN 13: 978-0-32180-924-7

Chapter 3 - Sections 3.1-3.12 - Exercises - Cumulative Problems - Page 135: 130

Answer

$$C_{18}H_{22}O_2$$

Work Step by Step

1. Find the empirical formula of estrone. $M(CO_2) = 44.0 \space g/mol$ $M(H_2O) = 18.0 \space g/mol$ $M(O_2) = 32.0 \space g/mol$ $$n(C) = n(CO_2) = \frac{5.545 \space g}{44.0 \space g/mol} = 0.126 \space mol$$ $$n(H) = 2 \times n(H_2O) = 2 \times \frac{1.388 \space g}{18.0 \space g/mol} = 0.154 \space mol$$ $$m(C) = 0.126 \space mol \times 12.0 \space g/mol = 1.51 \space g$$ $$m(H) = 0.154 \space mol \times 1.0 \space g/mol = 0.154 \space g$$ $$m(estrone) = m(C) + m(H) + m(O)$$ $$m(O) = m(estrone) - m(C) - m(H)$$ $$m(O) = 1.893 \space g - 1.51 \space g - 0.154 \space g = 0.229 \space g$$ $$n(O) = \frac{0.229 \space g}{16.0 \space g/mol} = 0.0143 \space mol$$ $$estrone = C_{0.126}H_{0.154}O_{0.0143}$$ $\div 0.0143$ $$estrone = C_{8.8}H_{10.8}O_{1} \approx C_9H_{11}O$$ 2. Calculate its molar mass and find the proportion. $M(C_9H_{11}O) = 12.0 * 9 + 1.0 * 11 + 16.0 = 135.0 \space g/mol$ $$\frac{270.36 \space g/mol}{135.0 \space g/mol} \approx 2$$ Thus: $$estrone = 2 * C_9H_{11}O = C_{18}H_{22}O_2$$
Update this answer!

You can help us out by revising, improving and updating this answer.

Update this answer

After you claim an answer you’ll have 24 hours to send in a draft. An editor will review the submission and either publish your submission or provide feedback.