Chemistry: A Molecular Approach (3rd Edition)

Published by Prentice Hall
ISBN 10: 0321809246
ISBN 13: 978-0-32180-924-7

Chapter 15 - Sections 15.1-15.12 - Exercises - Problems by Topic - Page 747: 75

Answer

$Ka = 3.612\times 10^{- 5}$

Work Step by Step

1. Drawing the equilibrium (ICE) table, we get these concentrations at equilibrium:** The image is in the end of this answer. -$[H_3O^+] = [Conj. Base] = x$ -$[Acid] = [Acid]_{initial} - x$ 2. Write the percent ionization equation, and find 'x': %ionization = $\frac{x}{[Initial Acid]} \times 100$ 1.55= $\frac{x}{ 0.148} \times 100$ 0.0155= $\frac{x}{ 0.148}$ $ 2.294\times 10^{- 3}= x$ Therefore: $[Conj. Base] and [H_3O^+] = 2.294\times 10^{- 3}$ And, $[Acid] = 0.148 - 2.294 \times 10^{-3} = 0.1457M$ 3. Write the Ka equation, and find its value: $Ka = \frac{[H_3O^+][Conj. Base]}{ [Acid]}$ $Ka = \frac{x^2}{[InitialAcid] - x}$ $Ka = \frac{( 2.294\times 10^{- 3})^2}{ 0.148- 2.294\times 10^{- 3}}$ $Ka = \frac{ 5.262\times 10^{- 6}}{ 0.1457}$ $Ka = 3.612\times 10^{- 5}$
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