Chemistry: A Molecular Approach (3rd Edition)

Published by Prentice Hall
ISBN 10: 0321809246
ISBN 13: 978-0-32180-924-7

Chapter 15 - Sections 15.1-15.12 - Exercises - Problems by Topic - Page 747: 74a

Answer

Percent ionization = $1.342 \%$

Work Step by Step

1. Drawing the equilibrium (ICE) table, we get these concentrations at equilibrium:** The image is in the end of this answer. -$[H_3O^+] = [Conj. Base] = x$ -$[Formic acid] = [Formic acid]_{initial} - x = 1 - x$ For approximation, we consider: $[Formic acid] = 1M$ 2. Now, use the Ka value and equation to find the 'x' value. $Ka = \frac{[H_3O^+][Conj. Base]}{ [Formic acid]}$ $Ka = 1.8 \times 10^{- 4}= \frac{x * x}{ 1}$ $Ka = 1.8 \times 10^{- 4}= \frac{x^2}{ 1}$ $ 1.8 \times 10^{- 4} = x^2$ $x = 1.342 \times 10^{- 2}$ Percent ionization: $\frac{ 1.342 \times 10^{- 2}}{ 1} \times 100\% = 1.342\%$ %ionization < 5% : Right approximation.
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