Chemistry 12th Edition

Published by McGraw-Hill Education
ISBN 10: 0078021510
ISBN 13: 978-0-07802-151-0

Chapter 14 - Chemical Equilibrium - Questions & Problems - Page 656: 14.25

Answer

$$K_c = 6.18 \times 10^{-4}$$

Work Step by Step

1. Calculate the initial concentration of $Br_2$: $$[Br_2]_{init} = \frac{1.05 \space moles}{0.980-L} = 1.07 \space M$$ 2. At equilibrium, these are the concentrations: $[Br_2] = 1.07 - x$ $[Br] = 0 + 2x$ 3. According to the problem: $1.20\% = \frac{x}{1.07} \times 100\%$. Solving for x: $$x = \frac{1.20 \times 1.07}{100} = 0.0128$$ 4. Substituting: $[Br_2] = 1.06 \space M$ $[Br] = 0.0256 \space M$ 5. Write the expression for $K_c$ and evaluate it: $$K_c = \frac{[Br]^2}{[Br_2]} = \frac{(0.0256)^2}{1.06} = 6.18 \times 10^{-4}$$
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