Answer
The particular solution that passes through the point $(0,3)$ is
$$y=3e^{-x/4}.$$
Work Step by Step
The solution $y^2=Ce^{-x/2}$ contains an arbitrary constant $C$. We will determine this constant by imposing that the graph of the function passes through the point $(0,3)$ which means that when we put $x=0$ we have to get $y=3$:
$$9=Ce^{-0/2} = Ce^0\Rightarrow C=9.$$
Further we have
$$y^2=9e^{-x/2}\Rightarrow y=\pm\sqrt{9e^{-x/2}} = \pm3e^{-x/4}.$$
Note that the only allowable solution for $y$ is with the $"+"$ sign because if we take the $"-"$ sign we will get that for $x=0$ $y=-3$, (while by taking $"+"$ we get what is required, i.e. for $x=0$ $y=3$).
Finally, the particular solution that passes through the point $(0,3)$ is
$$y=3e^{-x/4}.$$