Physics for Scientists and Engineers: A Strategic Approach with Modern Physics (3rd Edition)

Published by Pearson
ISBN 10: 0321740904
ISBN 13: 978-0-32174-090-8

Chapter 41 - Atomic Physics - Exercises and Problems - Page 1246: 32

Answer

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Work Step by Step

We know that the radial probability density $ P(r) $ is related to the square of the radial wave function $ R(r) $ and the factor $ r^2 $: $$ P(r) =4\pi r^2 |R_{1s}(r)|^2\tag 1 $$ For the hydrogen atom in the $ 1s $ state, the radial wave function is: $$ R_{1s}(r) = \frac{1}{\sqrt{\pi a_B^3}} e^{-r/a_B} $$ Plug into (1); $$ P(r) =4\pi r^2 \left[ \frac{1}{\sqrt{\pi a_B^3}} e^{-r/a_B}\right]^2 $$ $$ P(r) =4 \color{red}{\bf\not}\pi r^2 \cdot \frac{e^{-2r/a_B} }{ \color{red}{\bf\not}\pi a_B^3} $$ Simplifying: $$ P(r) = \frac{4e^{-2r/a_B}}{a_B^3}\; r^2\tag 2 $$ To find the value of $ r $ where the radial probability density peaks, we need to take the derivative of $ P(r) $ with respect to $ r $, set it equal to zero, and solve for $ r $. $$ \frac{d}{dr} P(r) = \frac{d}{dr} \left( \frac{4e^{-2r/a_B}}{a_B^3}\; r^2\right)=0 $$ We can factor out the constant $ \dfrac{4}{a_B^3} $, so the derivative becomes: $$ \frac{4}{a_B^3} \frac{d}{dr} \left( r^2 e^{-2r/a_B} \right)=0 $$ $$ \frac{d}{dr} \left( r^2 e^{-2r/a_B} \right)=0 $$ So $$ 2r e^{-2r/a_B} + r^2 \left( -\frac{2}{a_B} \right) e^{-2r/a_B}=0 $$ Factor out the common term $ e^{-2r/a_B} $. $$ 2r + \left( -\frac{2}{a_B} \right) r^2 =0 $$ Factor out the common term $2r$; $$ 2r\left[ 1 -\frac{r}{a_B} \right] =0 $$ This gives two solutions: $ r = 0 $ which corresponds to the minimum probability at the origin, or $ r = a_B $ at which the value of the radial probability density is maximum.
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