Physics for Scientists and Engineers: A Strategic Approach with Modern Physics (3rd Edition)

Published by Pearson
ISBN 10: 0321740904
ISBN 13: 978-0-32174-090-8

Chapter 41 - Atomic Physics - Exercises and Problems - Page 1245: 30

Answer

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Work Step by Step

We know that the radial wave function for the hydrogen atom in the 1s state is given by: $$ R_{1s}(r) = A e^{-r/a_B} $$ where $ A $ is the normalization constant, and $ a_B $ is the Bohr radius. The radial wave function must satisfy the normalization condition for the three-dimensional hydrogen atom $$ 4\pi \int_0^\infty |R_{1s}(r)|^2 r^2 \, dr = 1 $$ Substituting $ R_{1s}(r) = A e^{-r/a_B} $: $$ 4\pi\int_0^\infty \left( A e^{-r/a_B} \right)^2 r^2 \, dr = 1 $$ $$ 4\pi A^2 \int_0^\infty e^{-2r/a_B} r^2 \, dr = 1\tag 1 $$ We can use the provided integral formula: $$ \int_0^\infty x^n e^{-\alpha x} \, dx = \frac{n!}{\alpha^{n+1}} $$ where, in our case, $ x = r $, $ n = 2 $, $ \alpha = 2/a_B $. Thus, the integral becomes: $$ \int_0^\infty e^{-2r/a_B} r^2 \, dr = \frac{2!}{(2/a_B)^3} = \frac{2}{(2/a_B)^3} = \frac{a_B^3}{4} $$ Substitute this result into (1): $$ 4\pi A^2\cdot \frac{a_B^3}{4} = 1 $$ Solving for $ A^2 $: $$ A^2 = \frac{\color{red}{\bf\not} 4}{\color{red}{\bf\not} 4\pi a_B^3} $$ Taking the square root: $$ A = \frac{1}{\pi a_B^{3/2}} $$ Therefore, $$ \boxed{ A = \left(\pi a_B^3\right)^{-1/2}} $$
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