Physics for Scientists and Engineers: A Strategic Approach with Modern Physics (3rd Edition)

Published by Pearson
ISBN 10: 0321740904
ISBN 13: 978-0-32174-090-8

Chapter 41 - Atomic Physics - Exercises and Problems - Page 1245: 10

Answer

(a) Fluorine in the ground state. (b) Gallium in the ground state.

Work Step by Step

$$\color{blue}{\bf [a]}$$ We have $ 1s^2 \, 2s^2 \, 2p^5 $ where $ 1s^2 $: 2 electrons $ 2s^2 $: 2 electrons $ 2p^5 $: 5 electrons So, the total Electrons: $ 2 + 2 + 5 =\bf 9 \;\rm e^-$ The element with 9 electrons is $\underline{\color{red}{\text{ Fluorine (F)}}}$, which has an atomic number of $Z=9$. $\Rightarrow$ The configuration $ 1s^2 \, 2s^2 \, 2p^5 $ follows the expected electron filling order for fluorine, according to the Aufbau principle. Therefore, this configuration represents $\underline{\color{red}{\text{ the ground state for fluorine}}}$. $$\color{blue}{\bf [b]}$$ We have $ 1s^2 \, 2s^2 \, 2p^6 \, 3s^2 \, 3p^6 \, 4s^2 \, 3d^{10} \, 4p^1 $ where $ 1s^2 $: 2 electrons $ 2s^2 $: 2 electrons $ 2p^6 $: 6 electrons $ 3s^2 $: 2 electrons $ 3p^6 $: 6 electrons $ 4s^2 $: 2 electrons $ 3d^{10} $: 10 electrons $ 4p^1 $: 1 electron So, the total Electrons: $ 2 + 2 + 6 + 2 + 6 + 2 + 10 + 1 = \bf 31\;\rm e^- $ The element with 31 electrons is $\underline{\color{red}{\text{ gallium (Ga)}}}$, with an atomic number of $Z=31$. The usual ground-state configuration for gallium is indeed $ 1s^2 \, 2s^2 \, 2p^6 \, 3s^2 \, 3p^6 \, 4s^2 \, 3d^{10} \, 4p^1 $. Thus, this configuration represents$\underline{\color{red}{\text{ the ground state for gallium}}}$.
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