Answer
$E = (101,428~N/C)~\hat{j}$
Work Step by Step
We can find the distance from the center to each charge:
$r = \sqrt{(2.5~cm)^2+(2.5~cm)^2}$
$r = 3.54~cm$
$r = 0.0354~m$
We can find the magnitude of the electric field at the center due to $q_1$:
$E_1 = \frac{\vert q \vert}{4\pi~\epsilon_0~r^2}$
$E_1 = \frac{(10.0\times 10^{-9}~C)}{(4\pi)(8.854\times 10^{-12}~C^2/N~m^2)~(0.0354~m)^2}$
$E_1 = 71,720~N/C$
Since $q_1$ has a positive charge, the electric field at the center due to $q_1$ points away from $q_1$
We can express this electric field in unit-vector notation:
$E_1 = (71,720~cos~45^{\circ}~N/C)~\hat{i}+(-71,720~N/C~sin~45^{\circ}~N/C)~\hat{j}$
$E_1 = (50,714~N/C)~\hat{i}+(-50,714~N/C)~\hat{j}$
We can find the magnitude of the electric field at the center due to $q_2$:
$E_2 = \frac{\vert q \vert}{4\pi~\epsilon_0~r^2}$
$E_2 = \frac{(20.0\times 10^{-9}~C)}{(4\pi)(8.854\times 10^{-12}~C^2/N~m^2)~(0.0354~m)^2}$
$E_2 = 143,440~N/C$
Since $q_2$ has a negative charge, the electric field at the center due to $q_2$ points toward $q_2$
We can express this electric field in unit-vector notation:
$E_2 = (143,440~cos~45^{\circ}~N/C)~\hat{i}+(143,440~N/C~sin~45^{\circ}~N/C)~\hat{j}$
$E_2 = (101,428~N/C)~\hat{i}+(101,428~N/C)~\hat{j}$
We can find the magnitude of the electric field at the center due to $q_3$:
$E_3 = \frac{\vert q \vert}{4\pi~\epsilon_0~r^2}$
$E_3 = \frac{(20.0\times 10^{-9}~C)}{(4\pi)(8.854\times 10^{-12}~C^2/N~m^2)~(0.0354~m)^2}$
$E_3 = 143,440~N/C$
Since $q_3$ has a positive charge, the electric field at the center due to $q_3$ points away from $q_3$
We can express this electric field in unit-vector notation:
$E_3 = (-143,440~cos~45^{\circ}~N/C)~\hat{i}+(143,440~N/C~sin~45^{\circ}~N/C)~\hat{j}$
$E_3 = (-101,428~N/C)~\hat{i}+(101,428~N/C)~\hat{j}$
We can find the magnitude of the electric field at the center due to $q_4$:
$E_4 = \frac{\vert q \vert}{4\pi~\epsilon_0~r^2}$
$E_4 = \frac{(10.0\times 10^{-9}~C)}{(4\pi)(8.854\times 10^{-12}~C^2/N~m^2)~(0.0354~m)^2}$
$E_4 = 71,720~N/C$
Since $q_4$ has a negative charge, the electric field at the center due to $q_4$ points toward $q_4$
We can express this electric field in unit-vector notation:
$E_4 = (-71,720~cos~45^{\circ}~N/C)~\hat{i}+(-71,720~N/C~sin~45^{\circ}~N/C)~\hat{j}$
$E_4 = (-50,714~N/C)~\hat{i}+(-50,714~N/C)~\hat{j}$
We can find the net electric field:
$E = E_1+E_2+E_3+E_4$
$E = 0~\hat{i}+(101,428~N/C)~\hat{j}$
$E = (101,428~N/C)~\hat{j}$