General Chemistry (4th Edition)

Published by University Science Books
ISBN 10: 1891389602
ISBN 13: 978-1-89138-960-3

Chapter 14 Thermochemistry - Problems - Page 509: 14

Answer

$-1154\,kJ/mol$

Work Step by Step

We find: $\Delta n_{g}=4-(4+5)=-5$ $P\Delta V^{\circ}_{rxn}=\Delta n_{g}RT$ $=(-5)(8.3145\,Jmol^{-1}K^{-1})(298\,K)$ $=-12.3886\,kJ/mol$ $\Delta U^{\circ}_{rxn}=\Delta H^{\circ}_{rxn}-P\Delta V^{\circ}_{rxn}$ $=-1166\,kJ/mol-(-12.3886\,kJ/mol)$ $=-1154\,kJ/mol$
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