General Chemistry (4th Edition)

Published by University Science Books
ISBN 10: 1891389602
ISBN 13: 978-1-89138-960-3

Chapter 14 Thermochemistry - Problems - Page 509: 13

Answer

$-217.6\,kJ/mol$

Work Step by Step

We find: $\Delta n_{g}=0-1=-1$ $P\Delta V^{\circ}_{rxn}=\Delta n_{g}RT$ $=(-1)(8.3145\,Jmol^{-1}K^{-1})(298\,K)$ $=-2.4777\,kJ/mol$ $\Delta U^{\circ}_{rxn}=\Delta H^{\circ}_{rxn}-P\Delta V^{\circ}_{rxn}$ $=-220.1\,kJ/mol-(-2.4777\,kJ/mol)$ $=-217.6\,kJ/mol$
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