Chemistry (7th Edition)

Published by Pearson
ISBN 10: 0321943171
ISBN 13: 978-0-32194-317-0

Chapter 15 - Aqueous Equilibria: Acids and Bases - Section Problems - Page 650: 67

Answer

a) $[OH^-] = 4 \times 10^{- 11}M$, Acidic. b)$[OH^-] = 5 \times 10^{- 15}M$, Acidic. c) $[H_3O^+] = 1.786 \times 10^{- 6}M$, Acidic. d)$[H_3O^+] = 6.667 \times 10^{- 12}M$, Basic. e) $[H_3O^+] = 1 \times 10^{- 7}M$, Neutral.

Work Step by Step

If $[H_3O^+] > [OH^-]$, the solution is acidic. If $[H_3O^+] < [OH^-]$, the solution is basic. If $[H_3O^+] = [OH^-]$, the solution is neutral. a) $[H_3O^+] * [OH^-] = Kw = 10^{-14}$ $ 2.5 \times 10^{- 4} * [OH^-] = 10^{-14}$ $[OH^-] = \frac{10^{-14}}{ 2.5 \times 10^{- 4}}$ $[OH^-] = 4 \times 10^{- 11}$ - Acidic b) $[H_3O^+] * [OH^-] = Kw = 10^{-14}$ $ 2.0 * [OH^-] = 10^{-14}$ $[OH^-] = \frac{10^{-14}}{ 2.0}$ $[OH^-] = 5 \times 10^{- 15}$ - Acidic c) $[OH^-] * [H_3O^+] = Kw = 10^{-14}$ $ 5.6 \times 10^{- 9} * [H_3O^+] = 10^{-14}$ $[H_3O^+] = \frac{10^{-14}}{ 5.6 \times 10^{- 9}}$ $[H_3O^+] = 1.786 \times 10^{- 6}$ - Acidic d) $[OH^-] * [H_3O^+] = Kw = 10^{-14}$ $ 1.5 \times 10^{- 3} * [H_3O^+] = 10^{-14}$ $[H_3O^+] = \frac{10^{-14}}{ 1.5 \times 10^{- 3}}$ $[H_3O^+] = 6.667 \times 10^{- 12}$ - Basic e) $[OH^-] * [H_3O^+] = Kw = 10^{-14}$ $ 1 \times 10^{- 7} * [H_3O^+] = 10^{-14}$ $[H_3O^+] = \frac{10^{-14}}{ 1 \times 10^{- 7}}$ $[H_3O^+] = 1 \times 10^{- 7}$ - Neutral
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