University Physics with Modern Physics (14th Edition)

Published by Pearson
ISBN 10: 0321973615
ISBN 13: 978-0-32197-361-0

Chapter 42 - Molecules and Condensed Matter - Problems - Exercises - Page 1435: 42.16

Answer

See explanation.

Work Step by Step

a. If the average spacing is L, the volume occupied by each atom is $L^3 $. K and Br occur in equal amounts, so the density is the average mass of K and Br, divided by this volume. $$m_{average}=9.895\times10^{-26}kg$$ Now calculate the density in terms of L and solve. $$2.75\times10^3kg/m^3=\frac{9.895\times10^{-26}kg}{L^3}$$ $$L=3.30\times10^{-10} m$$ b. This is larger than the spacing in NaCl, but K and Br have larger atomic numbers than Na and Cl, respectively, and they are larger atoms.
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