Chemistry: The Central Science (13th Edition)

Published by Prentice Hall
ISBN 10: 0321910419
ISBN 13: 978-0-32191-041-7

Chapter 17 - Additional Aspects of Aqueous Equilibria - Exercises - Page 770: 17.59b

Answer

The concentration of $Ca^{2+}$ in the solution will increase.

Work Step by Step

As we discussed in 59a, the equilibrium will move to increase the consume of the added $Ca^{2+}$, and it will produce more $CaF_2(s)$. That follows the Le Chatelier's principle. But, that adjustment is not capable of consuming all of the added $Ca^{2+}$, which means that, the added concentration is higher than the consumed. Therefore, the concentration of $Ca^{2+}$ will increased.
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