Chemistry: The Central Science (13th Edition)

Published by Prentice Hall
ISBN 10: 0321910419
ISBN 13: 978-0-32191-041-7

Chapter 17 - Additional Aspects of Aqueous Equilibria - Exercises - Page 770: 17.53b

Answer

The $K_{sp}$ for $SrF_2$ is $2.7 \times 10^{-9}$ at $25 ^{\circ}C$

Work Step by Step

1. Calculate the molar mass: 87.62* 1 + 19* 2 = 125.62g/mol 2. Calculate the number of moles $n(moles) = \frac{mass(g)}{mm(g/mol)}$ $n(moles) = \frac{ 0.011}{ 125.62}$ $n(moles) = 8.757\times 10^{- 5}$ 3. Find the concentration in mol/L: - 100ml = 0.100L $C(mol/L) = \frac{n(moles)}{volume(L)}$ $ C(mol/L) = \frac{ 8.757\times 10^{- 5}}{ 0.1} $ $C(mol/L) = 8.757\times 10^{- 4}$ 4. Write the $K_{sp}$ expression: $ SrF_2(s) \lt -- \gt 1Sr^{2+}(aq) + 2F^{-}(aq)$ $ K_{sp} = [Sr^{2+}]^ 1[F^{-}]^ 2$ 5. Determine the ions concentrations: $[Sr^{2+}] = [SrF_2] * 1 = [8.757 \times 10^{-4}] * 1 = 8.757 \times 10^{-4}$ $[F^{-}] = [SrF_2] * 2 = 1.750 \times 10^{-3}$ 6. Calculate the $K_{sp}$: $ K_{sp} = (8.757 \times 10^{-4})^ 1 \times (1.750 \times 10^{-3})^ 2$ $ K_{sp} = (8.757 \times 10^{-4}) \times (3.067 \times 10^{-6})$ $ K_{sp} = (2.686 \times 10^{-9})$
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