Chemistry: A Molecular Approach (3rd Edition)

Published by Prentice Hall
ISBN 10: 0321809246
ISBN 13: 978-0-32180-924-7

Chapter 22 - Sections 22.1-22.9 - Exercises - Review Questions - Page 1069: 14

Answer

The process is detailed below.

Work Step by Step

To obtain elemental nitrogen, air is cooled below $-196^{\circ}C$, which causes it to liquefy. When the liquid air is warmed slightly, the nitrogen boils off, leaving liquid oxygen (which boils at the higher temperature of $-183^{\circ}C$ ). Passing the vaporized gas over hot copper metal purifies the nitrogen by removing residual oxygen (which reacts with the copper to form CuO). Nitrogen gas can also be separated from the other atmospheric gases by passing air through certain silicate materials called zeolites, which have channels of just the right diameter to separate gas molecules of different size.
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