Chemistry: A Molecular Approach (3rd Edition)

Published by Prentice Hall
ISBN 10: 0321809246
ISBN 13: 978-0-32180-924-7

Chapter 12 - Sections 12.1-12.8 - Exercises - Cumulative Problems - Page 592: 110

Answer

$104.6C^{\circ}$

Work Step by Step

We can find the required boiling point as follows: $n_{solute}=23.8mol-n_{H_2O}$ $n_{solute}=23.8mol-20.5mol=3.3mol$ Now the molarity of the solution is $m=(\frac{2.3mol\space solute}{20.5mol\space solv})(\frac{1mol\space solv}{18.0152g\space solv})(\frac{1000g\space solv}{1Kg\space solv})=8.9355m$ $\Delta T_b=K_b\times m$ $\Delta T_b=(0.512\frac{C^{\circ}}{m})(8.9355m)=4.6C^{\circ}$ $boiling \space point=100.0C^{\circ}+\Delta T_b$ We plug in the known values to obtain: $boiling \space point=100.0C^{\circ}+4.6C^{\circ}=104.6C^{\circ}$
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