Chemistry: A Molecular Approach (3rd Edition)

Published by Prentice Hall
ISBN 10: 0321809246
ISBN 13: 978-0-32180-924-7

Chapter 12 - Sections 12.1-12.8 - Exercises - Cumulative Problems - Page 592: 100

Answer

$51KJ/mol,-8.7C^{\circ}$

Work Step by Step

We know that $\Delta H_{soln}=-\Delta H_{lattice}+\Delta H_{hydr}$ We plug in the known values to obtain: $\Delta H_{soln}=(-599KJ/mol)+(-548KJ/mol)=51KJ/mol$ We find the heat gained by the solute $q_{KClO_4}=(10.0gKClO_4)(\frac{1mol\space KClO_4}{138.5489g\space KClO_4})(\frac{51KJ}{1mol.KClO_4})=3.610KJ$ and mass of solution is $m_{soln}=\frac{100.0mL\space sol(1.05g\space sol)}{1mL\space sol}$ $m_{soln}=105g\space soln$ Now $\Delta T=\frac{q_{soln}}{(m_{soln})(C)}$ We plug in the known values to obtain: $\Delta T=\frac{-3.6810\times 10^3J}{(105g)(4.05\frac{J}{g.C^{\circ}})}$ $\Delta T=-8.7C^{\circ}$
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