Chemistry (7th Edition)

Published by Pearson
ISBN 10: 0321943171
ISBN 13: 978-0-32194-317-0

Chapter 19 - Nuclear Chemistry - Section Problems - Page 837: 56

Answer

$1.1\times10^{6}\,y$

Work Step by Step

Number of moles $n=\frac{\text{mass in grams}}{\text{molar mass}}=\frac{1.0\times10^{-3}\,g}{79\,g/mol}=1.2658\times10^{-5}\,mol$ Number of particles $N=n\times\text{Avogadro number}$ $=1.2658\times10^{-5}\times6.022\times10^{23}=7.62265\times10^{18}$ Decay rate= $1.5\times10^{5}\,dps=kN=k\times7.62265\times10^{18}$ $\implies k=\frac{1.5\times10^{5}/s}{7.62265\times10^{18}}=1.9678\times10^{-14}\,s^{-1}$ $t_{1/2}=\frac{0.693}{k}=\frac{0.693}{1.9678\times10^{-14}\,s^{-1}}=3.5217\times10^{13}\,s$ $=3.5217\times10^{13}\,s\times\frac{1\,h}{3600\,s}\times\frac{1\,d}{24\,h}\times\frac{1\,y}{365\,d}=1.1\times10^{6}\,y$
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