Chemistry (4th Edition)

Published by McGraw-Hill Publishing Company
ISBN 10: 0078021529
ISBN 13: 978-0-07802-152-7

Chapter 15 - Questions and Problems - Page 708: 15.32

Answer

$K_p$ for this reaction at 800 K is equal to 5.20

Work Step by Step

1. $P_{CO} = P_{Cl_2} = 0.497$ atm 2. $[COCl_2] = (3.00 \times 10^{-2} mol)/1.50 L = 0.0200 \space M$ 3. $P_{COCl_2} = (0.0200)(0.08206)(800) = 1.31$ atm 4. Write the equilibrium constant expression: - The exponent of each concentration is equal to its balance coefficient. $$K_P = \frac{[Products]}{[Reactants]} = \frac{P_{ COCl_2 }}{P_{ CO }P_{ Cl_2 }}$$ 5. Substitute the values and calculate the constant value: $$K_P = \frac{( 1.31 )}{( 0.497 )( 0.497 )} = 5.20$$
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