Answer
$S$ is a linearly dependent set of vectors.
Work Step by Step
Since one can have the combination
$$(2,-1)=3(1,0)-(1,1)$$ then we get the non trivial combination
$$(2,-1)-3(1,0)+(1,1)=(0,0).$$
Hence, $S$ is a linearly dependent set of vectors.
Or, instead, since $R^2$ has dimension $2$ then the maximum number of linearly independent vectors is $2$ but $S$ has $3$ vectors then it must be linearly dependent.