University Physics with Modern Physics (14th Edition)

Published by Pearson
ISBN 10: 0321973615
ISBN 13: 978-0-32197-361-0

Chapter 42 - Molecules and Condensed Matter - Problems - Discussion Questions - Page 1434: Q42.6

Answer

The energy levels are closer together because of the larger reduced mass of the deuterium molecule.

Work Step by Step

Equation 42.4 gives the reduced mass of a diatomic molecule. In $D_2$, each deuterium atom has about twice the mass as ordinary hydrogen, so the reduced mass is twice as great. Equation 42.6 shows that the moment of inertia for $D_2$ is twice as great as that of $H_2$, so the rotational energy levels will be closer together by a factor of 2, because their spacing is inversely proportional to the moment of inertia (equation 42.3). The vibrational energy levels will be closer together by a factor of $\sqrt{2}$, because their spacing is inversely proportional to the square root of reduced mass (equation 42.7).
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