Physics: Principles with Applications (7th Edition)

Published by Pearson
ISBN 10: 0-32162-592-7
ISBN 13: 978-0-32162-592-2

Chapter 28 - Quantum Mechanics of Atoms - General Problems - Page 828: 51

Answer

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Work Step by Step

Use equation 27–14 to solve for the radius of the n = 1 orbit when Z = 92. The radius is inversely proportional to the atomic number. $$r_n=\frac{n^2}{Z}(0.529\times10^{-10}m)= \frac{1^2}{92}(0.529\times10^{-10}m)= 5.75\times10^{-13}m $$ To estimate the energy required to remove that innermost electron, estimate the electron’s energy (which will be negative as it is in a bound state). The energy required to remove it is the magnitude of that energy, because when the electron is free, it has E = 0. Use equation 27–15b. The energy of the electron in a Bohr orbit is proportional to the square of the atomic number. Use Z = 92, because the innermost electron is not shielded from the 92 protons in the nucleus. $$|E_n|=(13.6eV) \frac{Z^2}{n^2}=(13.6eV) \frac{92^2}{1^2}=1.15\times10^5 eV$$ It would take about 115 keV to remove the innermost electron of a uranium atom.
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