Physics for Scientists and Engineers: A Strategic Approach with Modern Physics (3rd Edition)

Published by Pearson
ISBN 10: 0321740904
ISBN 13: 978-0-32174-090-8

Chapter 40 - One-Dimensional Quantum Mechanics - Exercises and Problems - Page 1213: 23

Answer

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Work Step by Step

To prove that the superposition \( \psi(x) = A\psi_1(x) + B\psi_2(x) \) is a solution to the Schrödinger equation, we need use the time-independent Schrödinger equation of $$ \frac{d^2 \psi_{(x)}}{dx^2} = -\frac{2m}{\hbar^2} [E - U(x)] \psi_{(x)}\tag 1 $$ We know that $ \psi_1(x) $ and $ \psi_2(x) $ are solutions to the time-independent Schrödinger equation for the same potential energy $ U(x)$. So the superposition is $$ \psi(x) = A\psi_1(x) + B\psi_2(x)\tag 2 $$ where $ A $ and $ B $ are constants. The second derivative of $\psi_{(x)}$ with respect to $x$ is given by $$ \frac{d^2 \psi_{(x)}}{dx^2} = \frac{d^2}{dx^2} \left[A \psi_1(x) + B \psi_2(x)\right]$$ Substituted from (2), $$ \frac{d^2 \psi_{(x)}}{dx^2} = A \frac{d^2 \psi_1(x)}{dx^2} + B \frac{d^2 \psi_2(x)}{dx^2} \tag 3 $$ Plugging from (1), The second derivatives of $\psi_1(x)$ and $\psi_2(x)$ are given by $$ \frac{d^2 \psi_1(x)}{dx^2} = -\frac{2m}{\hbar^2} [E - U(x)] \psi_1(x) \tag 4$$ $$ \frac{d^2 \psi_2(x)}{dx^2} = -\frac{2m}{\hbar^2} [E - U(x)] \psi_2(x) \tag 5$$ Substituting these expressions from (4) and (5) into (3). $$ \frac{d^2 \psi_{(x)}}{dx^2} = A \left(-\frac{2m}{\hbar^2} [E - U(x)] \psi_1(x)\right) + B \left(-\frac{2m}{\hbar^2} [E - U(x)] \psi_2(x)\right) $$ Factoring out $-\dfrac{2m}{\hbar^2} [E - U(x)]$ from both terms: $$ \frac{d^2 \psi_{(x)}}{dx^2} = -\frac{2m}{\hbar^2} [E - U(x)] \left(A \psi_1(x) + B \psi_2(x)\right) $$ Noting that $ A \psi_1(x) + B \psi_2(x)=\psi_{(x)} $, from (1), So $$ \boxed{\frac{d^2 \psi_{(x)}}{dx^2} = -\frac{2m}{\hbar^2} [E - U(x)] \psi_{(x)}}$$ This final expression is identical to the original Schrödinger equation for $\psi_{(x)}$. Therefore, $\psi_{(x)}$, as defined by the linear combination of $\psi_1(x)$ and $\psi_2(x)$, is also a solution to the Schrödinger equation.
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