Physics for Scientists and Engineers: A Strategic Approach with Modern Physics (3rd Edition)

Published by Pearson
ISBN 10: 0321740904
ISBN 13: 978-0-32174-090-8

Chapter 40 - One-Dimensional Quantum Mechanics - Exercises and Problems - Page 1213: 18

Answer

${\bf 2.25}\;\rm N/m$

Work Step by Step

We know that $$ E_n = \left(n - \frac{1}{2}\right)\hbar \omega_e $$ where $n=1,2,3,...$ So, the longest wavelength of light that can be absorbed is given by $$E_{\rm photon}=E_{3}-E_{2}=\dfrac{hc}{\lambda}\tag 1$$ where $$E_{n+1}-E_{n}= \left(n+1 - \frac{1}{2}\right)\hbar \omega_e- \left(n - \frac{1}{2}\right)\hbar \omega_e =\hbar \omega_e $$ Plug into (1); $$\hbar \omega_e =\dfrac{hc}{\lambda}$$ Recalling that the angular frequency of a mass on a spring is given by $\omega=\sqrt{k/m}$. So, $$\hbar \sqrt{\dfrac{k}{m}} =\dfrac{hc}{\lambda}$$ Solving for $k$; $$ \sqrt{\dfrac{k}{m}} =\dfrac{hc}{\hbar\lambda}=\dfrac{2\pi hc}{h\lambda}= \dfrac{ 2\pi c}{\lambda}$$ $$ \dfrac{k}{m} = \dfrac{ 4\pi^2 c^2}{\lambda^2}$$ $$k = \dfrac{ 4\pi^2m c^2}{\lambda^2}$$ Plug the known; $$k = \dfrac{ 4 \pi^2 (9.11\times 10^{-31})(3\times 10^8)^2}{(1200\times 10^{-9})^2}$$ $$ k =\color{red}{\bf 2.25}\;\rm N/m$$
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