Physics for Scientists and Engineers: A Strategic Approach with Modern Physics (3rd Edition)

Published by Pearson
ISBN 10: 0321740904
ISBN 13: 978-0-32174-090-8

Chapter 40 - One-Dimensional Quantum Mechanics - Exercises and Problems - Page 1213: 19

Answer

${\bf 1.35}\;\rm N/m$

Work Step by Step

We know that $$ E_n = \left(n - \frac{1}{2}\right)\hbar \omega_e $$ where $n=1,2,3,...$ So, $$E_{\rm photon}=E_{3}-E_{2}=\dfrac{hc}{\lambda}\tag 1$$ where $$E_{n+1} = \left(n+1 - \frac{1}{2}\right)\hbar \omega_e= 2.8\;\rm eV $$ $$ \left(n+ \frac{1}{2}\right)\hbar \omega_e= 2.8 \tag 2 $$ and, $$ E_{n}= \left(n - \frac{1}{2}\right)\hbar \omega_e= 2.0\;\rm eV$$ So, $$ n =\dfrac{ 2.0}{\hbar \omega_e}+ \frac{1}{2} $$ Plug into (2); $$ \left(\dfrac{ 2.0}{\hbar \omega_e}+ \frac{1}{2}+ \frac{1}{2}\right)\hbar \omega_e= 2.8 $$ $$ \left(\dfrac{ 2.0}{\hbar \omega_e}+ 1\right)\hbar \omega_e= 2.8 $$ $$ \dfrac{ 2.0\hbar \omega_e}{\hbar \omega_e}+ \hbar \omega_e = 2.8 $$ Hence, $$ \hbar \omega_e=2.8-2=0.8\;\rm eV$$ Recalling that the angular frequency of a mass on a spring is given by $\omega=\sqrt{k/m}$ $$ \hbar \sqrt{\dfrac{k}{m}} = 0.8 e$$ where $e$ for converting from eV to J. Solving for $k$; $$ \sqrt{\dfrac{k}{m}} =\dfrac{ 0.8 e}{\hbar}$$ $$ \dfrac{k}{m} =\dfrac{ 0.8^2 e^2}{\hbar^2}$$ $$ k=\dfrac{ 0.8^2 e^2 m}{\hbar^2}$$ Plug the known; $$ k=\dfrac{ 0.8^2 (1.6\times 10^{-19})^2 (9.11\times 10^{-31})}{(1.05\times 10^{-34})^2}$$ $$ k=\color{red}{\bf 1.35}\;\rm N/m$$
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