Introductory Chemistry (5th Edition)

Published by Pearson
ISBN 10: 032191029X
ISBN 13: 978-0-32191-029-5

Chapter 14 - Acids and Bases - Exercises - Problems - Page 523: 64

Answer

(a) $[OH^-] = 7.7 \times 10^{-12}M$: Acidic solution; (b) $[OH^-] = 1.1 \times 10^{-3}M$: Basic solution; (c) $[OH^-] = 1.9 \times 10^{-11}M$: Acidic solution; (d) $[OH^-] = 1.6 \times 10^{-6}M$: Basic solution;

Work Step by Step

If $[H_3O^+] > [OH^-]$, the solution is acidic. If $[OH^-] > [H_3O^+]$, the solution is basic. 1. Calculate the hydroxide ion concentration: $[H_3O^+] * [OH^-] = Kw = 10^{-14}$ $1.3 \times 10^{-3} * [OH^-] = 10^{-14}$ $[OH^-] = \frac{10^{-14}}{1.3 \times 10^{-3}}$ $[OH^-] = 7.7 \times 10^{-12}$ 2. Calculate the hydroxide ion concentration: $[H_3O^+] * [OH^-] = Kw = 10^{-14}$ $9.1 \times 10^{-12} * [OH^-] = 10^{-14}$ $[OH^-] = \frac{10^{-14}}{9.1 \times 10^{-12}}$ $[OH^-] = 1.1 \times 10^{-3}$ 3. Calculate the hydroxide ion concentration: $[H_3O^+] * [OH^-] = Kw = 10^{-14}$ $5.2 \times 10^{-4} * [OH^-] = 10^{-14}$ $[OH^-] = \frac{10^{-14}}{5.2 \times 10^{-4}}$ $[OH^-] = 1.9 \times 10^{-11}$ 4. Calculate the hydroxide ion concentration: $[H_3O^+] * [OH^-] = Kw = 10^{-14}$ $6.1 \times 10^{-9} * [OH^-] = 10^{-14}$ $[OH^-] = \frac{10^{-14}}{6.1 \times 10^{-9}}$ $[OH^-] = 1.6 \times 10^{-6}$
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