General Chemistry: Principles and Modern Applications (10th Edition)

Published by Pearson Prentice Hal
ISBN 10: 0132064529
ISBN 13: 978-0-13206-452-1

Chapter 15 - Priciples of Chemical Equilibrium - Exercises - Direction and Extent of Chemical Change - Page 690: 29

Answer

Since $Q_c \ne K_c$, the mixture is not at equilibrium, and the compounds cannot be maintained indefinitely at these concentrations.

Work Step by Step

1. Calculate all the concentrations: $$[SO_2] = ( 3.6 )/(7.2) = 0.50 M$$ $$[O_2] = ( 2.2 )/(7.2) = 0.31 M$$ $$[SO_3] = ( 1.8 )/(7.2) = 0.25 M$$ - The exponent of each concentration is equal to its balance coefficient. $$Q_c = \frac{[Products]}{[Reactants]} = \frac{[ SO_3 ] ^{ 2 }}{[ SO_2 ] ^{ 2 }[ O_2 ]}$$ 2. Substitute the values and calculate the quocient value: $$Q_c = \frac{( 0.25 )^{ 2 }}{( 0.50 )^{ 2 }( 0.31 )} = 0.81$$ Since $Q_c \ne K_c$, the mixture is not at equilibrium, and the compounds cannot be maintained indefinitely at these concentrations.
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