Chemistry: The Molecular Nature of Matter and Change 7th Edition

Published by McGraw-Hill Education
ISBN 10: 007351117X
ISBN 13: 978-0-07351-117-7

Chapter 18 - Problems - Page 820: 18.78

Answer

Percent dissociation = 1.1%

Work Step by Step

1. Draw the ICE table for this equilibrium: $$\begin{vmatrix} Compound& [ C_6H_5COOH ]& [ C_6H_5COO^- ]& [ H_3O^+ ]\\ Initial& 0.55 & 0 & 0 \\ Change& -x& +x& +x\\ Equilibrium& 0.55 -x& 0 +x& 0 +x\\ \end{vmatrix}$$ 2. Write the expression for $K_a$, and substitute the concentrations: - The exponent of each concentration is equal to its balance coefficient. $$K_C = \frac{[Products]}{[Reactants]} = \frac{[ C_6H_5COO^- ][ H_3O^+ ]}{[ C_6H_5COOH ]}$$ $$K_a = \frac{(x)(x)}{[ C_6H_5COOH ]_{initial} - x}$$ 3. Assuming $ 0.55 \gt\gt x:$ $$K_a = \frac{x^2}{[ C_6H_5COOH ]_{initial}}$$ $$x = \sqrt{K_a \times [ C_6H_5COOH ]_{initial}} = \sqrt{ 6.3 \times 10^{-5} \times 0.55 }$$ $x = 5.9 \times 10^{-3} $ 4. Test if the assumption was correct: $$\frac{ 5.9 \times 10^{-3} }{ 0.55 } \times 100\% = 1.1 \%$$ 5. The percent is less than 5%. Thus, it is correct to say that $x = 5.9 \times 10^{-3} $
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